{"id":12013,"date":"2022-11-05T15:22:49","date_gmt":"2022-11-05T07:22:49","guid":{"rendered":"https:\/\/www.htech360.com\/?p=12013"},"modified":"2022-11-25T11:21:00","modified_gmt":"2022-11-25T03:21:00","slug":"b23f558024","status":"publish","type":"post","link":"https:\/\/www.htech360.com\/a\/12013","title":{"rendered":"PEM\u7535\u89e3\u69fd\u964d\u672c\u548c\u53d1\u5c55\u5c55\u671b"},"content":{"rendered":"
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\u8bf4\u660e\uff1a\u672c\u6587\u548c\u4e0a\u7bc7\u6765\u81ea\u540c\u4e00\u6587\u732e\u7f16\u8bd1\u6574\u7406\uff01<\/span><\/strong><\/span><\/p>\n

\u6839\u636e\u4ee5\u4e0a\u7ae0\u8282\u5206\u89e3PEM\u7535\u89e3\u69fd\u7684\u6784\u6210\u548c\u6210\u672c\u5360\u6bd4\uff0c\u4ee5\u53ca\u8be6\u7ec6\u8bf4\u660e\u5404\u90e8\u4ef6\u53d1\u6325\u7684\u4f5c\u7528\uff0c\u6211\u4eec\u5927\u81f4\u5bf9\u672a\u6765\u5982\u4f55\u80fd\u591f\u5236\u9020\u51fa\u6027\u4ef7\u6bd4\u9ad8\u7684PEM\u7535\u89e3\u69fd\u6216\u8005\u662f\u5982\u4f55\u80fd\u63d0\u9ad8\u6027\u80fd\u7684\u540c\u65f6\u964d\u4f4e\u5176\u9ad8\u6602\u7684\u6210\u672c\u6709\u4e86\u4e9b\u57fa\u672c\u7684\u5224\u65ad\u3002\u5982\u4e0b\u56fe\u6240\u793a\uff0c\u53e6\u6839\u636e\u8fd9\u4e9b\u7ec6\u8282\u4e0b\u9762\u9488\u5bf9\u6027\u5c55\u5f00\u8bf4\u660e\uff1a<\/span><\/p>\n

\"PEM\u7535\u89e3\u69fd\u964d\u672c\u548c\u53d1\u5c55\u5c55\u671b\"<\/section>\n

\"PEM\u7535\u89e3\u69fd\u964d\u672c\u548c\u53d1\u5c55\u5c55\u671b\"PEMWE\u5173\u952e\u6750\u6599\u7684\u672a\u6765\u7814\u7a76\u65b9\u5411<\/span><\/p>\n

\u4e00\u3001\u5408\u9002\u7684\u50ac\u5316\u5242<\/strong><\/span><\/section>\n
PEMWE\u7684\u5de5\u4f5c\u6761\u4ef6(\u5373\u4f4epH\u503c\u548c\u9ad8\u7535\u6d41\u5bc6\u5ea6)\u9650\u5236\u4e86\u7535\u50ac\u5316\u5242\u7684\u9009\u62e9\uff0c\u53ea\u80fd\u9009\u62e9\u7a00\u6709\u548c\u6602\u8d35\u7684\u8d35\u91d1\u5c5e(\u5982\u94c2\u548cIr)\u3002\u8fd9\u963b\u788d\u4e86PEM\u5236\u6c22\u6280\u672f\u7684\u5927\u89c4\u6a21\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5728\u4e0d\u727a\u7272\u7535\u50ac\u5316\u5242\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u524d\u63d0\u4e0b\uff0c\u51cf\u5c11Pt(\u22640.2 mg\/cm2)\u548cIr(\u22640.3 mg\/cm2)\u5728\u7535\u50ac\u5316\u5242\u4e2d\u7684\u4f7f\u7528\u91cf\u662f\u5341\u5206\u5fc5\u8981\u7684\u3002\u4e3a\u4e86\u5e73\u8861\u7535\u50ac\u5316\u5242\u7684\u6210\u672c\u3001\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u6bd4\u4f8b\u5173\u7cfb\uff0c\u53ef\u4ee5\u5f97\u51fa\u4ee5\u4e0b\u8bbe\u8ba1\u601d\u8def:<\/span><\/section>\n
(a)\u5f15\u5165\u975e\u8d35\u91d1\u5c5e\u6210\u5206\u7a00\u91ca\u7535\u50ac\u5316\u5242\u4e2d\u7684\u8d35\u91d1\u5c5e\u542b\u91cf;<\/span><\/section>\n
(b)\u5f00\u53d1\u9ad8\u5bfc\u7535\u6027\u548c\u5927\u8868\u9762\u79ef\u652f\u6491\u50ac\u5316\u5242\uff0c\u4ee5\u63d0\u9ad8\u94f1\u7684\u8d28\u91cf\u6d3b\u6027;<\/span><\/section>\n
(c)\u8c03\u8282\u7535\u50ac\u5316\u5242\u7684\u7535\u5b50\u7ed3\u6784\u548c\u5c40\u90e8\u73af\u5883\uff0c\u4ee5\u63d0\u9ad8\u5176\u56fa\u6709\u6d3b\u6027;<\/span><\/section>\n
(d)\u63ed\u793a\u50ac\u5316\/\u5931\u6d3b\u673a\u7406\uff0c\u89e3\u51b3\u7a33\u5b9a\u6027\u63d0\u9ad8\u95ee\u9898\u3002<\/span><\/section>\n

\u8fd1\u5e74\u6765\uff0c\u8bb8\u591a\u4f4e\u94c2\/\u94f1\uff0c\u751a\u81f3\u65e0\u94c2\/\u94f1\u7684\u7535\u50ac\u5316\u5242\u88ab\u5f00\u53d1\u51fa\u6765\u3002\u7136\u800c\uff0c\u5728PEM\u5236\u6c22\u4e2d\u8fd8\u8fdc\u8fdc\u6ca1\u6709\u5e94\u7528\u5230\u3002\u4e00\u65b9\u9762\uff0c\u8fd9\u4e9b\u7535\u50ac\u5316\u5242\u7684\u6027\u80fd\u8bc4\u4f30\u662f\u57fa\u4e8e\u4e09\u7535\u6781\u7cfb\u7edf\uff0c\u4e0ePEMWE\u7684\u64cd\u4f5c\u6761\u4ef6\u4e0d\u540c\uff0c\u8fd9\u662f\u4e00\u4e2a\u5b9e\u9a8c\u5ba4\u89c4\u6a21\u7684\u8bc4\u4f30\u3002\u5927\u591a\u6570\u7535\u50ac\u5316\u5242\u5728PEMWE\u4e2d\u4e0d\u80fd\u8868\u73b0\u51fa\u5b89\u57f9\u7ea7\u7535\u6d41\u5bc6\u5ea6\u548c\u5e74\u4efd\u7ea7\u522b\u7684\u5bff\u547d\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u8fd9\u4e9b\u66ff\u4ee3\u7535\u50ac\u5316\u5242\u7684\u5236\u5907\u6280\u672f\u96be\u4ee5\u8fbe\u5230\u5343\u514b\u7ea7\u3002\u56e0\u6b64\uff0c\u5728\u8fdb\u4e00\u6b65\u7684\u7814\u7a76\u4e2d\uff0c\u5e94\u8003\u8651\u7535\u50ac\u5316\u5242\u5728PEMWE\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u548c\u5927\u89c4\u6a21\u5236\u5907\u5de5\u827a\u3002<\/span><\/p>\n

\u4e8c\u3001\u65b0\u4e00\u4ee3\u8d28\u5b50\u4ea4\u6362\u819c\uff08PEM\uff09<\/strong><\/p>\n

PEM\u7684\u5316\u5b66\u3001\u529b\u5b66\u548c\u70ed\u6027\u80fd\u4e0ePEMWE\u7684\u6027\u80fd\u548c\u5bff\u547d\u5bc6\u5207\u76f8\u5173\u3002\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u6b63\u662fPEM\u7684\u7279\u6027\u51b3\u5b9a\u4e86PEMWE\u7684\u5de5\u4f5c\u6761\u4ef6(\u5982\u6e29\u5ea6\u548c\u538b\u529b)\u3002\u4ee5Nafion\u819c\u4e3a\u4f8b\uff0c\u5176\u6700\u9ad8\u5de5\u4f5c\u6e29\u5ea6\u4e3a90\u2103\uff0c\u8d85\u8fc7\u8fd9\u4e2a\u6e29\u5ea6PEM\u5c31\u4f1a\u8131\u6c34\u964d\u89e3\uff0c\u5bfc\u81f4PEMWE\u5931\u6d3b\u3002\u5c3d\u7ba1\u9ad8\u6e29\u53ef\u4ee5\u964d\u4f4e\u6c34\u7535\u89e3\u7684\u80fd\u5792\uff0c\u52a0\u5feb\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u7531\u4e8ePEMWE\u7684\u5de5\u4f5c\u6e29\u5ea6\u88ab\u9650\u5236\u572890\u2103\u4ee5\u4e0b\uff0c\u8fd9\u9650\u5236\u4e86\u819c\u6548\u7387\u7684\u63d0\u9ad8\u3002<\/span><\/section>\n
\u540c\u6837\uff0c\u9ad8\u538b\u6709\u5229\u4e8e\u50a8\u6c22\uff0c\u4f46\u4e5f\u4f1a\u52a0\u901f\u6c14\u4f53\u4ea7\u7269\u7684\u4ea4\u53c9\uff0c\u5bfc\u81f4\u7535\u6d41\u6548\u7387\u548cH2\u7eaf\u5ea6\u964d\u4f4e\u3002PEM\u7684\u53e6\u4e00\u4e2a\u7f3a\u70b9\u662f\u6210\u672c\u9ad8\u6e90\u4e8e\u9aa8\u67b6\u7ed3\u6784\u4e2d\u7684\u6c1f\u3002\u56e0\u6b64\uff0c\u7406\u60f3\u7684PEM\u9700\u8981\u5177\u6709\u4f4e\u6210\u672c\u3001\u4f18\u5f02\u7684\u5316\u5b66\u548c\u673a\u68b0\u7a33\u5b9a\u6027\u3001\u9ad8\u8d28\u5b50\u4f20\u5bfc\u6027\u548c\u4f4e\u6c14\u4f53\u6e17\u900f\u6027\u3002\u76ee\u524d\u7684PEM\u53ef\u4ee5\u4ece\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\u8fdb\u884c\u5f00\u53d1\u548c\u6539\u8fdb:<\/span><\/section>\n

(a)\u901a\u8fc7\u6dfb\u52a0PEM\u5939\u5c42\u7ed3\u6784\u5bf9PEM\u8fdb\u884c\u6539\u6027\u964d\u4f4e\u6c14\u4f53\u6e17\u900f;<\/span><\/p>\n

(b)\u5728\u4fdd\u8bc1\u6c34\u5316\u7a0b\u5ea6\u7684\u540c\u65f6\uff0c\u63d0\u9ad8\u5176\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u673a\u68b0\u6027\u80fd;<\/span><\/p>\n

(c)\u63d0\u9ad8\u5176\u5de5\u4f5c\u6e29\u5ea6\u4e0a\u9650\uff0c\u63d0\u9ad8\u5176\u70ed\u7a33\u5b9a\u6027;<\/span><\/p>\n

(d)\u5f00\u53d1\u6210\u672c\u8f83\u4f4e\u7684\u819c(\u4f8b\u5982\u78b3\u6c22\u57fa\u819c)\u3002<\/span><\/p>\n

\u4e09\u3001\u6539\u826fMEA\u52a0\u5de5\u5de5\u827a<\/strong><\/span><\/section>\n

MEA\u7531PEM\u3001\u9634\u6781\u548c\u9633\u6781\u50ac\u5316\u5242\u5c42\u7ec4\u6210\uff0c\u6709\u65f6\u5305\u542b\u4e24\u4e2aGDL\u3002\u5b83\u662f\u7535\u89e3\u6c34\u7684\u4e3b\u6218\u573a\u3002\u56e0\u6b64\uff0c\u8c03\u6574MEA\u7684\u5236\u4f5c\u53ef\u4ee5\u4ece\u6839\u672c\u4e0a\u63d0\u9ad8PEMWE\u7684\u6210\u672c\u3001\u6027\u80fd\u548c\u5bff\u547d\u3002\u6587\u4e2d\u63cf\u8ff0\u7684\u6539\u8fdb\u4e0d\u4ec5\u9650\u4e8e\u7535\u50ac\u5316\u5242\u7684\u6539\u6027\uff0c\u8fd8\u5305\u62ec\u5bf9MEA\u7684\u5236\u5907\u5de5\u827a\u8fdb\u884c\u4e86\u4f18\u5316\uff0c\u5305\u62ec\u6d46\u6599\u6210\u5206\u3001\u6d82\u819c\u65b9\u6cd5\u3001\u70ed\u538b\u6761\u4ef6\u7b49\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u6539\u8fdbMEA\u7684\u5236\u5907\u5de5\u827a\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u9014\u5f84:<\/span><\/p>\n

(a)\u4f18\u5316\u6cb9\u58a8\u6210\u5206(\u5982\u50ac\u5316\u5242\u3001\u8f7d\u4f53\u6210\u5206\u3001\u79bb\u805a\u4f53\u548c\u5176\u4ed6\u9644\u52a0\u8d1f\u8f7d)\uff0c\u5f00\u53d1\u8054\u5408\u5206\u6563\u6280\u672f(\u5982\u8d85\u58f0\u548c\u526a\u5207\u5e94\u529b\u5206\u6563)\uff0c\u63d0\u9ad8\u9897\u7c92\u76f4\u5f84\u3001\u6d41\u53d8\u6027\u3001Zeta\u7535\u4f4d\u7b49\u7269\u7406\u6027\u80fd\uff0c\u4ece\u800c\u5b9e\u73b0\u5747\u5300\u7684MEA;<\/span><\/section>\n
(b)\u9009\u62e9\u5408\u9002\u7684\u6d82\u5c42\u65b9\u6cd5(\u5982\u7535\u5316\u5b66\u6c89\u79ef\u6cd5\u3001\u8d85\u58f0\u55b7\u6d82\u6cd5\u3001\u8f6c\u5370\u6cd5)\uff0c\u589e\u5f3aMEA\u4e0a\u4e09\u76f8\u754c\u9762\u7684\u4f20\u8d28\u80fd\u529b\uff0c\u63d0\u9ad8\u8d35\u91d1\u5c5e\u5229\u7528\u7387\uff0c\u8fdb\u800c\u63d0\u9ad8\u5176\u50ac\u5316\u6027\u80fd;<\/span><\/section>\n
(c)\u5bf9\u73b0\u6709\u6d82\u88c5\u8bbe\u5907\u8fdb\u884c\u6539\u9020\uff0c\u5b9e\u73b0\u8f8a\u5bf9\u8f8a\u6d82\u88c5\uff0c\u6ee1\u8db3\u5de5\u4e1a\u9700\u6c42;<\/span><\/section>\n
(d)\u8c03\u8282\u6700\u4f73\u70ed\u538b\u6e29\u5ea6\u3001\u538b\u529b\u548c\u6301\u7eed\u65f6\u95f4\uff0c\u4ee5\u5b9e\u73b0\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684\u534f\u540c\u589e\u5f3a;<\/span><\/section>\n

(e)\u8c03\u6574\u6d46\u6599\u6210\u5206\u3001\u6d82\u8986\u65b9\u6cd5\u548c\u70ed\u538b\u6761\u4ef6\u7684\u517c\u5bb9\u6027\uff0c\u5b9e\u73b0\u9ad8\u6548\u7a33\u5b9a\u7684MEA\u7684\u7cbe\u786e\u6784\u5efa\u3002<\/span><\/p>\n

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\u4e94\u3001\u4f18\u5316BP\u8bbe\u8ba1<\/span><\/strong><\/span><\/p>\n

BP\u7684\u529f\u80fd\u5305\u62ec\u5bfc\u7535\u3001\u63d0\u4f9b\u6c34\u8def\u3001\u5206\u79bbO2\u548cH2\u3001\u652f\u6491\u7535\u89e3\u69fd\u548c\u63d0\u4f9b\u70ed\u4f20\u5bfc\u3002\u56e0\u6b64\uff0c\u677f\u6750\u6750\u6599\u8981\u6c42\u5bfc\u7535\u6027\u9ad8\u3001\u8010\u8150\u8680\u3001\u900f\u6c14\u6027\u4f4e\u3001\u673a\u68b0\u5f3a\u5ea6\u5f3a\u3001\u5bfc\u70ed\u7cfb\u6570\u9ad8\u3002\u9540\u6709\u8d35\u91d1\u5c5e\u7684\u949b(\u5982Au\u548cPt)\u4ecd\u7136\u662f\u6700\u597d\u7684\u9009\u62e9\u3002\u5f15\u5165\u8d35\u91d1\u5c5e\u5927\u5927\u589e\u52a0\u4e86\u6210\u672c\u3002\u56e0\u6b64\uff0c\u5bfb\u627e\u964d\u4f4e\u6210\u672c\u7684\u89e3\u51b3\u65b9\u6848\u662fbp\u53d1\u5c55\u7684\u4e3b\u8981\u96be\u70b9\u3002\u6700\u6709\u6548\u7684\u65b9\u6cd5\u662f\u901a\u8fc7\u6539\u8fdb\u6d82\u5c42\u6210\u5206\u6216\u5236\u5907\u5de5\u827a\u6765\u964d\u4f4e\u6d82\u5c42\u6750\u6599\u4e2d\u8d35\u91d1\u5c5e\u7684\u542b\u91cf\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u964d\u4f4e\u6210\u672c\uff0c\u975e\u8d35\u91d1\u5c5e\u6d82\u5c42(\u5982Zr\u548cNb\u6d82\u5c42)\u4e5f\u6b63\u5728\u5f00\u53d1\u4e2d\u3002\u4f18\u5316bp\u7684\u53e6\u4e00\u4e2a\u65b9\u5411\u662f\u5176\u6d41\u573a\u7684\u5408\u7406\u8bbe\u8ba1\u3002\u76ee\u524d\uff0cBP\u7684\u6d41\u573a\u8bbe\u8ba1\u4e3b\u8981\u6709\u4ee5\u4e0b\u4e09\u79cd\u7c7b\u578b:<\/span><\/p>\n

(a)\u91c7\u7528\u949b\u7f51\u4f5c\u4e3a\u5e73\u677f\u5206\u79bb\u5668\u7247\uff0c\u591a\u5b54\u949b\u70e7\u7ed3\u4f5c\u4e3aGDL;<\/span><\/section>\n
(b)\u4f7f\u7528\u5e26\u8680\u523b\u901a\u9053\u7684\u539a\u949b\u677f;<\/span><\/section>\n

(c)\u4f7f\u7528\u51b2\u538b\u6709\u51f9\u69fd\u7684\u949b\u677f\u3002<\/span><\/p>\n

\u7136\u800c\uff0c\u4e0a\u8ff0\u6d41\u573a\u8981\u4e48\u5904\u7406\u6210\u672c\u9ad8\uff0c\u8981\u4e48\u9020\u6210\u5e94\u529b\u7578\u53d8\uff0c\u5bfc\u81f4\u65e0\u6cd5\u653e\u5927\u7528\u4e8e\u5b9e\u9645\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5408\u7406\u8bbe\u8ba1BP\u6d41\u573a\u4e5f\u662f\u4e00\u4e2a\u70ed\u70b9\u95ee\u9898\u3002<\/span><\/section>\n
<\/section>\n

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