\u5236\u6c22\u7535\u6781\u7684\u91cd\u8981\u6027<\/span><\/p>\n<\/section>\n \n<\/section>\n<\/section>\n \u7535\u50ac\u5316\u6c34\u5236\u6c22\uff0c\u7ed3\u5408\u4ee5\u5149\u4f0f\u3001\u98ce\u7535\u4e3a\u4ee3\u8868\u7684\u53ef\u518d\u751f\u80fd\u6e90\u53d1\u7535\u7cfb\u7edf,\u80fd\u591f\u4e3a\u5c06\u6765\u53ef\u6301\u7eed\u7684\u6c22\u80fd\u4f9b\u5e94\u63d0\u4f9b\u7406\u60f3\u7684\u6280\u672f\u624b\u6bb5\u3002\u7535\u50ac\u5316\u6c34\u88c2\u89e3\u53cd\u5e94\u53ef\u5206\u6210\u6790\u6c22\uff08HER\uff09\u548c\u6790\u6c27\uff08OER\uff09\u4e24\u4e2a\u534a\u53cd\u5e94\u3002\u7136\u800c,\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u6d89\u53ca\u56db\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b,\u52a8\u529b\u5b66\u7f13\u6162,\u662f\u7535\u89e3\u6c34\u7684\u74f6\u9888\u53cd\u5e94\u3002\u76ee\u524d,\u78b1\u6027\u7535\u89e3\u69fd\u662f\u6700\u6210\u719f\u7684\u5546\u4e1a\u7535\u89e3\u6c34\u6280\u672f,\u4f7f\u7528\u954d\u7535\u6781\u4f5c\u6790\u6c27\u7535\u6781,\u7531\u4e8e\u5176\u672c\u5f81\u50ac\u5316\u6d3b\u6027\u4e0d\u9ad8,\u4f7f\u7535\u89e3\u6c34\u6548\u7387\u4e25\u91cd\u53d7\u9650\u3002\u56e0\u6b64,\u4ece\u7eff\u6c22\u7ecf\u6d4e\u6218\u7565\u89d2\u5ea6\u51fa\u53d1,\u5f00\u53d1\u7a33\u5b9a\u7684\u3001\u9ad8\u6d3b\u6027\u7535\u6781\u5bf9\u4e8e\u5b9e\u73b0\u6c22\u80fd\u548c\u53ef\u518d\u751f\u80fd\u6e90\u7684\u6709\u6548\u5229\u7528\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/span><\/p>\n \u4e3a\u4e86\u63d0\u9ad8\u954d\u7535\u6781\u7684\u672c\u5f81\u50ac\u5316\u6d3b\u6027,\u901a\u8fc7\u5bf9\u56fa\u76f8\u787c\u5316\u3001\u7535\u5316\u5b66\u6c27\u5316\u3001\u5feb\u901f\u79bb\u5b50\u4ea4\u6362\u7b49\u8868\u9762\u6539\u6027\u65b9\u6cd5,\u5236\u5907\u4e86\u591a\u79cd\u9ad8\u6027\u80fd\u7684\u954d\u7f51\u6750\u6599\u4f5c\u4e3a\u78b1\u6027\u6c34\u6c27\u5316\u7535\u6781,\u6bd4\u8f83\u954d\u7535\u6781\u6750\u6599\u8868\u9762\u7ed3\u6784\u4e0e\u6d3b\u6027\u4e4b\u95f4\u7684\u6784\u6548\u5173\u7cfb,\u4e3a\u63d0\u9ad8\u6c22\u6c14\u5236\u5907\u6548\u7387\u8fdb\u884c\u5b9e\u9a8c\u3002<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n \n <\/p>\n<\/section>\n \u954d\u7f51\u7535\u6781\u56fa\u76f8\u787c\u5316\u6cd5<\/span><\/p>\n<\/section>\n \u7528\u56fa\u76f8\u787c\u5316\u65b9\u6cd5\u5c06\u954d\u7f51\u7247\u8f6c\u5316\u4e3a\u9ad8\u6027\u80fd\u7684\u591a\u5c42\u787c\u5316\u954d\u78b1\u6027\u6790\u6c27\u7535\u6781\u3002\u787c\u5316\u63d0\u9ad8\u4e86\u954d\u7f51\u7535\u6781\u7684\u672c\u5f81\u50ac\u5316\u6d3b\u6027\uff0c\u787c\u5316\u7684\u954d\u7247\u5728\u7535\u5316\u5b66OER\u6d4b\u8bd5\u8fc7\u7a0b\u4e2d\u5b58\u5728\u6d3b\u5316\u73b0\u8c61,\u5728\u7535\u6781\u8868\u9762\u539f\u4f4d\u751f\u6210\u4e86\u7eb3\u7c73\u7247\u8584\u819c,\u50ac\u5316\u8fc7\u7a0b\u4e2d\u542b\u6709\u504f\u787c\u9178\u7684\u03b3-Ni OOH\u4e3a\u4e3b\u8981\u50ac\u5316\u6d3b\u6027\u76f8\u3002\u4e0e\u666e\u901a\u6c9f\u901a\u954d\u7f51\u7247\u76f8\u6bd4,\u6d3b\u5316\u7684\u787c\u5316\u954d\u7247\u7684\u50ac\u5316\u6d3b\u6027\u63d0\u9ad8\u4e86\u8fd1\u5341\u500d,\u5e76\u4e14\u5728\u8d85\u8fc71500\u5c0f\u65f6\u7684\u65f6\u95f4\u5185\u8868\u73b0\u51fa\u663e\u8457\u7684\u50ac\u5316\u7a33\u5b9a\u6027\u3002\u787c\u5316\u954d\u7535\u5316\u5b66\u6d3b\u5316\u671f\u95f4\u589e\u5f3a\u7684\u50ac\u5316\u6027\u80fd\u5f97\u76ca\u4e8e\u7f9f\u57fa\u6c27\u5316\u7269\u7684\u8584\u7eb3\u7c73\u7247\u7ed3\u6784\uff08\u5373\u51e0\u4f55\u4f18\u5316\uff09\u548c\u504f\u787c\u9178\u76d0\u5bf9\u7f9f\u57fa\u6c27\u5316\u7269\u7684\u7535\u5b50\u7ed3\u6784\u8c03\u63a7\u4e4b\u95f4\u534f\u540c\u4f18\u5316\u4f5c\u7528\uff08\u5373\u7535\u5b50\u4f18\u5316\uff09\u3002<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n <\/p>\n<\/section>\n <\/p>\n <\/p>\n \n<\/section>\n<\/section>\n \u7528\u6c2f\u79bb\u5b50\u8010\u8150\u8680\u6027\u7684OER\u50ac\u5316\u7535\u6781\uff0c\u5c06\u954d\u7f51\u7247\u76f4\u63a5\u70ed\u787c\u5316\u5904\u7406,\u7136\u540e\u8fdb\u884c\u7535\u5316\u5b66\u6c27\u5316\u5236\u5907\u4e00\u79cd\u591a\u5c42\u6790\u6c27\u7535\u6781\u3002\u53ef\u6ee1\u8db3\u9633\u6781\u6750\u6599\u7528\u4e8e\u6d77\u6c34\u5206\u89e3\u7684\u591a\u79cd\u9700\u6c42\uff0c\u8be5\u7535\u6781\u7531\u8d77\u4e3b\u8981\u50ac\u5316\u4f5c\u7528\u7684\u8868\u9762\u6c27\u5316\u7684\u954d\u7f51\u5c42\u3001\u8d77\u6297\u8150\u8680\u6027\u4f5c\u7528\u7684\u954d\u7f51\u4e2d\u95f4\u5c42\u548c\u8d77\u652f\u6491\u4f5c\u7528\u7684\u954d\u7f51\u57fa\u5e95\u7ec4\u6210\u3002\u7535\u6781\u8868\u9762\u5c42\u6c27\u5316Ni Fe Bx\u5c42\u4e2d\u787c\u7269\u79cd\u4ee5\u504f\u787c\u9178\u76d0\u7684\u5f62\u5f0f\u5b58\u5728,\u76f8\u5e94\u5b9e\u9a8c\u7ed3\u5408\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u8bc1\u660e\u5176\u5b58\u5728\u6709\u52a9\u4e8e\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u50ac\u5316\u6d3b\u6027\u76f8\u03b3-\uff08Ni,Fe\uff09OOH\u7684\u751f\u6210\u4e0e\u7a33\u5b9a,\u540c\u65f6,\u901a\u8fc7\u4f18\u5316\u6d3b\u6027\u76f8\u7684\u7535\u5b50\u7ed3\u6784\u63d0\u9ad8\u4e86\u7535\u6781\u6750\u6599\u7684\u672c\u5f81\u50ac\u5316\u6d3b\u6027\u3002\u76f8\u5173\u542b\u6c2f\u4f53\u7cfb\u4e0b\u7684\u7a33\u5b9a\u6027\u7ed3\u679c\u548c\u8150\u8680\u884c\u4e3a\u7814\u7a76\u8bc1\u5b9eNi Fe Bx\u4e2d\u95f4\u5c42\u7684\u80fd\u591f\u6709\u6548\u9632\u6b62\u9633\u6781\u6750\u6599\u5728\u542b\u6c2f\u79bb\u5b50\u7684\u7535\u89e3\u8d28\u4e2d\u8fc7\u5ea6\u6c27\u5316\u8150\u8680\u3002<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n <\/p>\n <\/p>\n <\/p>\n \n<\/section>\n<\/section>\n \u5728\u6700\u5c0f\u7684\u8fc7\u7535\u52bf\u4e0b\u5e94\u7528\u9ad8OER\u7535\u6d41\u5bc6\u5ea6,\u5236\u5907\u6709\u6210\u672c\u6548\u76ca\u7684\u9ad8\u6027\u80fdOER\u7535\u6781,\u5bf9\u63d0\u9ad8\u7535\u89e3\u7cfb\u7edf\u6548\u7387,\u5b9e\u73b0\u5de5\u4e1a\u5236\u6c22\u662f\u5fc5\u4e0d\u53ef\u5c11\u7684\u3002\u4e00\u79cd\u7ecf\u6d4e\u9ad8\u6548\u4e14\u5de5\u4e1a\u517c\u5bb9\u7684\u65b9\u6cd5,\u5728\u5ba4\u6e29\u4e0b\u5feb\u901f\u5236\u5907\u4e86\u5e73\u65b9\u7c73\u7ea7\u8868\u9762\u6539\u6027\u954d\u7f51\u7535\u6781,\u5b9e\u73b0\u4e86\u5728\u8fc7\u7535\u52bf\u4e3a217 m V\u548c300 m V\u65f6\u53ef\u5206\u522b\u8fbe10 mA cm-2\u548c100 mA cm-2\u7535\u6d41\u5bc6\u5ea6\u7684OER\u50ac\u5316\u6d3b\u6027,\u53ef\u7a33\u5b9a\u8d85\u8fc71900\u5c0f\u65f6\u3002\u5728\u5de5\u4e1a\u7535\u89e3\u69fd\u5b9e\u9645\u6d4b\u8bd5\u4e2d,\u8fbe\u5230300 mA cm-2\u7535\u6d41\u5bc6\u5ea6\u6240\u9700\u7535\u538b\u5c0f\u4e8e2 V\u3002\u8fd9\u79cd\u8868\u9762\u6539\u6027\u954d\u7f51\u7535\u6781\u65b9\u6cd5\u6709\u671b\u5728\u5b9e\u9645\u5de5\u4e1a\u5e94\u7528\u4e2d\u53d1\u6325\u66f4\u5927\u7684\u5546\u4e1a\u4ef7\u503c\u3002\u00a0<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n <\/p>\n <\/p>\n \n