{"id":19883,"date":"2023-04-11T16:57:37","date_gmt":"2023-04-11T08:57:37","guid":{"rendered":"https:\/\/www.htech360.com\/?p=19883"},"modified":"2023-04-11T16:57:37","modified_gmt":"2023-04-11T08:57:37","slug":"mtu-%e7%a2%b3%e9%85%b8%e7%9b%90%e8%b6%85%e7%bb%93%e6%9e%84%e5%9b%ba%e4%bd%93%e7%87%83%e6%96%99%e7%94%b5%e6%b1%a0-cssfc-%e5%9c%a8%e8%be%83%e4%bd%8e%e7%9a%84%e5%b7%a5%e4%bd%9c%e6%b8%a9%e5%ba%a6","status":"publish","type":"post","link":"https:\/\/www.htech360.com\/a\/19883","title":{"rendered":"MTU \u78b3\u9178\u76d0\u8d85\u7ed3\u6784\u56fa\u4f53\u71c3\u6599\u7535\u6c60 (CSSFC) \u5728\u8f83\u4f4e\u7684\u5de5\u4f5c\u6e29\u5ea6\u4e0b\u63d0\u4f9b\u66f4\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6"},"content":{"rendered":"

\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60 (SOFC) \u5177\u6709\u9ad8\u80fd\u6548\u548c\u71c3\u6599\u7075\u6d3b\u6027\uff0c\u4f46\u9700\u8981\u8f83\u9ad8\u7684\u5de5\u4f5c\u6e29\u5ea6\u3002\u867d\u7136\u964d\u4f4e SOFC \u7684\u5de5\u4f5c\u6e29\u5ea6\u53ef\u4ee5\u6700\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u6750\u6599\u964d\u89e3\u5e76\u80fd\u591f\u4f7f\u7528\u66f4\u4fbf\u5b9c\u7684\u6750\u6599\uff0c\u4f46\u7535\u89e3\u8d28\u548c\u7535\u6781\u7535\u963b\u90fd\u4f1a\u968f\u7740\u5de5\u4f5c\u6e29\u5ea6\u7684\u964d\u4f4e\u5448\u6307\u6570\u589e\u52a0\u3002<\/span><\/p>\n

\u73b0\u5728\uff0c\u5bc6\u6b47\u6839\u7406\u5de5\u5927\u5b66\u7684\u7814\u7a76\u4eba\u5458<\/span>\u5c55\u793a\u4e86<\/span><\/a>\u4e00\u79cd\u78b3\u9178\u76d0\u8d85\u7ed3\u6784\u56fa\u4f53\u71c3\u6599\u7535\u6c60 (CSSFC)\uff0c\u5176\u4e2d\u5728\u591a\u5b54\u7684\u63ba\u9490\u4e8c\u6c27\u5316\u94c8\u5c42\u4e2d\u539f\u4f4d\u751f\u6210\u8d85\u7ed3\u6784\u78b3\u9178\u76d0\uff0c\u5f62\u6210\u4e00\u79cd\u72ec\u7279\u7684\u7535\u89e3\u8d28\uff0c\u5177\u6709 0.17 S\u22c5cm \u22121 \u7684\u8d85\u9ad8\u79bb\u5b50<\/span>\u7535\u5bfc\u7387<\/span><\/sup>\u5728 550 \u00b0C\u3002CSSFC \u5728\u8f83\u4f4e\u7684\u5de5\u4f5c\u6e29\u5ea6\u4e0b\u4f7f\u7528\u78b3\u6c22\u5316\u5408\u7269\u71c3\u6599\u663e\u793a\u51fa\u66f4\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u3002\u4e00\u7bc7\u5173\u4e8e\u8fd9\u9879\u5de5\u4f5c\u7684\u5f00\u653e\u83b7\u53d6\u8bba\u6587\u53d1\u8868\u5728<\/span>\u7f8e\u56fd\u56fd\u5bb6\u79d1\u5b66\u9662\u9662\u520a<\/span><\/i>(PNAS) \u4e0a\u3002<\/span><\/p>\n

\"\u71c3\u6599\u7535\u6c60\u56fe\u5f62\u65b0\u53d1\u660e\u5782\u76f4<\/a><\/p>\n

\u2026\u4f7f\u7528\u78b3\u6c22\u5316\u5408\u7269\u71c3\u6599\u7684\u4f4e\u6e29 SOFC (LT-SOFC) \u4f1a\u56e0\u6e29\u5ea6\u4e0b\u964d\u548c\u79ef\u78b3\uff08\u7126\u5316\uff09\u800c\u5bfc\u81f4\u6781\u5316\u635f\u5931\u3002\u53d1\u751f\u8fd9\u79cd\u60c5\u51b5\u662f\u56e0\u4e3a 1) \u7531\u4e8e\u5f3a C-H \u952e\uff0c\u78b3\u6c22\u5316\u5408\u7269\u6c27\u5316\u52a8\u529b\u5b66\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u6781\u5176\u7f13\u6162\uff0c\u4ee5\u53ca 2) \u78b3\u6c89\u79ef\u901a\u8fc7\u8986\u76d6\u50ac\u5316\u4f4d\u70b9\u4f7f\u7535\u6781\u5931\u6d3b\u3002<\/span><\/em><\/p>\n

\u2026\u2026\u6539\u5584 LT-SOFC \u78b3\u6c22\u5316\u5408\u7269\u6c27\u5316\u548c\u51cf\u5c11\u7126\u5316\u7684\u5173\u952e\u7b56\u7565\u4e4b\u4e00\u662f\u63d0\u9ad8\u7535\u89e3\u8d28\u7684\u6c27\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u2026\u6709\u4e24\u79cd\u5e38\u89c4\u7b56\u7565\u53ef\u4ee5\u63d0\u9ad8 LT-SOFC \u4e2d\u7535\u89e3\u8d28\u7684\u6c27\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u5373\u964d\u4f4e\u7535\u89e3\u8d28\u539a\u5ea6\u548c\u5f00\u53d1\u5feb\u901f\u79bb\u5b50\u5bfc\u4f53\u3002\u8d85\u8584\u7535\u89e3\u8d28\u819c\u9700\u8981\u5148\u8fdb\u7684\u6280\u672f\uff0c\u4e0d\u53ef\u907f\u514d\u5730\u589e\u52a0\u4e86\u5236\u9020\u6210\u672c\u548c\u590d\u6742\u6027\u3002\u5c3d\u7ba1\u6c27\u5316\u94cb\u7531\u4e8e\u5176\u4e30\u5bcc\u7684\u6c27\u7a7a\u4f4d\u800c\u8868\u73b0\u51fa\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u6c27\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u4f46\u5b83\u4eec\u5728 SOFC \u8fd0\u884c\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u5dee\u4f1a\u963b\u788d\u5176\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u9700\u8981\u5176\u4ed6\u7b56\u7565\u6765\u5f00\u53d1\u9ad8\u6548\u7684\u79bb\u5b50\u5bfc\u4f53\u3002<\/span><\/em><\/p>\n

-\u82cf<\/span>\u7b49\u3002<\/span><\/i><\/div>\n

 <\/p><\/blockquote>\n

\u8be5\u56e2\u961f\u5047\u8bbe\u7194\u878d\u78b3\u9178\u76d0\u548c\u56fa\u4f53\u79bb\u5b50\u5bfc\u4f53\u4e4b\u95f4\u7684\u8fde\u7eed\u754c\u9762\u53ef\u4ee5\u6784\u6210\u6c27\u79bb\u5b50\u7684\u5feb\u901f\u4f20\u8f93\u901a\u9053\u2014\u2014\u5373\uff0c\u56fa\u4f53\u79bb\u5b50\u5bfc\u4f53\u4e0a\u7684\u8fd9\u79cd\u78b3\u9178\u76d0\u8d85\u7ed3\u6784\u5c06\u662f\u6c27\u79bb\u5b50\u8d85\u5bfc\u4f53\u3002<\/span><\/p>\n

\u4e3a\u4e86\u9a8c\u8bc1\u8fd9\u4e00\u5047\u8bbe\uff0c\u6211\u4eec\u901a\u8fc7\u96c6\u6210 LiNi\u00a0<\/span>0.8<\/span><\/sub>\u00a0Co\u00a0<\/span>0.15<\/span><\/sub>\u00a0Al\u00a0<\/span>0.05<\/span><\/sub>\u00a0O\u00a0<\/span>2<\/span><\/sub>\u00a0(NCAL) \u9634\u6781\u3001\u591a\u5b54 Ce\u00a0<\/span>0.8<\/span><\/sub>\u00a0Sm\u00a0<\/span>0.2<\/span><\/sub>\u00a0O\u00a0<\/span>1.9<\/span><\/sub>\u00a0(SDC) \u7535\u89e3\u8d28\u548c Ni-BaZr\u00a0<\/span>0.1<\/span><\/sub>\u00a0Ce\u00a0<\/span>0.7<\/span><\/sub>\u00a0Y\u00a0<\/span>0.1<\/span><\/sub>\u00a0Yb\u00a0<\/span>0.1<\/span><\/sub>\u5236\u9020\u4e86\u4e00\u79cd\u88c5\u7f6eO\u00a0<\/span>3\u2013\u03b4<\/span><\/sub>(BZCYYb) \u9633\u6781\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\u4f7f\u7528\u4e00\u6b65\u5e72\u538b\u7a0b\u5e8f\uff0c\u65e0\u9700\u9ad8\u6e29\u70e7\u7ed3\u3002\u7535\u6781\u548c\u7535\u89e3\u8d28\u5728\u7cfb\u7edf\u4e2d\u4fdd\u6301\u591a\u5b54\u548c\u7eb3\u7c73\u6676\u4f53\u7ed3\u6784\u3002\u7136\u540e\uff0c\u591a\u5b54 NCAL \u548c SDC \u5c42\u4e2d\u7684\u7194\u878d\u78b3\u9178\u76d0\u5728\u7535\u6c60\u8fd0\u884c\u6761\u4ef6\u4e0b\u539f\u4f4d\u751f\u6210\uff0c\u4ece\u800c\u5f62\u6210\u78b3\u9178\u76d0\u8d85\u7ed3\u6784\u71c3\u6599\u7535\u6c60 (CSSFC)\u3002<\/span><\/em><\/p>\n

\u6b64\u5916\uff0cCSSFC \u5728 550\u00b0C \u65f6\u8868\u73b0\u51fa 0.17 S\u22c5cm\u00a0<\/span>-1<\/span><\/sup>\u7684\u8d85\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u5bfc\u81f4\u524d\u6240\u672a\u6709\u7684\u9ad8\u5f00\u8def\u7535\u538b (OCV) \u548c\u975e\u5e38\u9ad8\u7684\u5cf0\u503c\u529f\u7387\u5bc6\u5ea6 (PPD) \u4ee5\u53ca\u51fa\u8272\u7684\u6297\u7ed3\u7126\u6027550\u00b0C \u7684\u7532\u70f7\u71c3\u6599\u3002<\/span><\/em><\/p>\n

-\u82cf<\/span>\u7b49\u3002<\/span><\/i><\/div>\n

 <\/p><\/blockquote>\n

\"Pnas.2208750119fig01\"<\/a><\/p>\n

(A)<\/span><\/b>\u4f20\u7edf SOFC\u3001\u591a\u5b54 SOFC \u548c CSSFC \u7684\u793a\u610f\u56fe\u3002<\/span>(B)\u4ee5 Ni-BZCYYb \u4f5c\u4e3a\u9633\u6781\u5728 550 \u00b0C \u4e0b\u4ee5 CH\u00a0<\/span><\/b>4<\/span><\/sub>\u8fd0\u884c\u7684\u4e0d\u540c\u71c3\u6599\u7535\u6c60\u914d\u7f6e\u7684 IVP \u6027\u80fd\u3002<\/span>(C)<\/span><\/b>\u5177\u6709\u6216\u4e0d\u5177\u6709\u78b3\u9178\u76d0\u6539\u6027\u7684\u4e0d\u540c\u7535\u89e3\u8d28\u7684\u6c27\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027 Arrhenius \u56fe\u3002<\/span>(D)<\/span><\/b>\u00a0Ar \u6c14\u6c1b\u4e2d\u4e0d\u540c\u7535\u89e3\u8d28\u7684 DSC \u56fe\u3002\u82cf<\/span>\u7b49\u3002<\/span><\/i><\/p>\n

\n

\u901a\u8baf\u4f5c\u8005\u80e1\u4e91\u822a\u4f30\u8ba1CSSFC\u71c3\u6cb9\u6548\u7387\u53ef\u8fbe60%\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u5185\u71c3\u673a\u7684\u5e73\u5747\u71c3\u6cb9\u6548\u7387\u5728 35% \u5230 30% \u4e4b\u95f4\u3002CSSFC \u66f4\u9ad8\u7684\u71c3\u6cb9\u6548\u7387\u53ef\u80fd\u4f1a\u964d\u4f4e\u8f66\u8f86\u7684\u4e8c\u6c27\u5316\u78b3\u6392\u653e\u91cf\u3002<\/span><\/p>\n

\u53c2\u8003\u6587\u732e\uff1aHanrui Su\u3001Wei Zhang \u548c Yun Hang Hu (2023) \u201cCarbonate-superstructured solid fuel cells with hydrocarbon fuels\u201d PNAS\u00a0 doi: 10.1073\/pnas.2208750119<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/www.greencarcongress.com\/2023\/04\/20230409-mtu.html<\/p>\n

 <\/p>\n","raw":"","protected":false},"excerpt":{"rendered":"

\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60 (SOFC) \u5177\u6709\u9ad8\u80fd\u6548\u548c\u71c3\u6599\u7075\u6d3b\u6027\uff0c\u4f46\u9700\u8981\u8f83\u9ad8\u7684\u5de5\u4f5c\u6e29\u5ea6\u3002\u867d\u7136\u964d\u4f4e SOFC \u7684\u5de5\u4f5c\u6e29\u5ea6 […]<\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[36],"tags":[],"post_thumbnail_image":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7519f00dc200c-500wi","content_first_image":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7519f00dc200c-500wi","post_medium_image_300":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7519f00dc200c-500wi","post_thumbnail_image_624":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7519f00dc200c-500wi","post_frist_image":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7519f00dc200c-500wi","post_medium_image":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7519f00dc200c-500wi","post_large_image":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7519f00dc200c-500wi","post_full_image":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7519f00dc200c-500wi","post_all_images":[{"imagesurl":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7519f00dc200c-500wi","id":"image0"},{"imagesurl":"https:\/\/bioage.typepad.com\/.a\/6a00d8341c4fbe53ef02b7517aaa18200b-500wi","id":"image1"}],"videoAdId":"","listAd":"0","listAdId":"","listAdEvery":5,"total_comments":0,"category_name":"\u56fa\u4f53\u71c3\u6599\u7535\u6c60SOFC","post_date":"2023-04-11","like_count":"0","praiseWord":"\u9f13\u52b1","copyright_state":"","excitationAd":"0","rewardedVideoAdId":"","detailAdId":"","detailAd":"0","enterpriseMinapp":"1","audios":[],"postImageUrl":"https:\/\/file.htech360.com\/110\/uploads\/2022\/04\/htech360.mini_.logo_.jpg","avatarurls":[],"related_posts":null,"pageviews":1121,"next_post_id":19951,"next_post_title":"\u4e00\u79cd\u78b3\u9178\u76d0\u8d85\u7ed3\u6784\u56fa\u4f53\u71c3\u6599\u7535\u6c60 (CSSFC)","previous_post_id":19603,"previous_post_title":"\u65e5\u672c\u7535\u88c5\u516c\u53f8\u5f00\u53d1SOFC\u71c3\u6599\u7535\u6c60","_links":{"self":[{"href":"https:\/\/www.htech360.com\/wp-json\/wp\/v2\/posts\/19883"}],"collection":[{"href":"https:\/\/www.htech360.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.htech360.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.htech360.com\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/www.htech360.com\/wp-json\/wp\/v2\/comments?post=19883"}],"version-history":[{"count":0,"href":"https:\/\/www.htech360.com\/wp-json\/wp\/v2\/posts\/19883\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.htech360.com\/wp-json\/wp\/v2\/media?parent=19883"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.htech360.com\/wp-json\/wp\/v2\/categories?post=19883"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.htech360.com\/wp-json\/wp\/v2\/tags?post=19883"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}